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They make a tool specifically for taking these apart . Using a fine pick works for me though.

ie:

http://shop.willyselectronics.com/browse.cfm/ht-2023-pin-insertion-molex-/4,8872.html


Yes, have one of those tools and it works for the Molex connectors which have the round pins and hollow round mating parts. But each different type of connector will need a different tool and/or technique to release the pins.